Journal of Organometallic Chemistry

The synthesis and reactions of certain disilanes containing chloromethyl groups

M Kumada, M Ishikawa

Index: Kumada,M.; Ishikawa,M. Journal of Organometallic Chemistry, 1964 , vol. 1, p. 411 - 419

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Citation Number: 46

Abstract

Abstract An investigation has been made of the synthesis of two new organofunctional disilanes,(dichloromethyl) pentamethyldisilane and 1, 2-bis (chloromethyl) tetramethyldisilane, and some reactions of these and the previously reported (chloromethyl) pentamethyldisilane.(Dichloromethyl) pentamethyldisilane undergoes intramolecular rearrangement with anhydrous aluminum chloride to give either (trimethylsilyl)( ...