Cyclo-hydrosilylation: A novel route to siloxetanes and silanones
TH Lane, CL Frye
Index: Lane,T.H.; Frye,C.L. Journal of Organometallic Chemistry, 1979 , vol. 172, p. 213 - 221
Full Text: HTML
Citation Number: 0
Abstract
Abstract A novel and convenient method for the apparent liquid phase generation of dimethylsilanone, Me 2 Si O (D 1), based on readily obtainable reactants and employing conventional temperatures (50–150) is reported herein. Platinum catalyzed hydrosilylation of vinyldimethylcaarbinoxydimethylsilane (I) appears to proceed by an exclusively intramolecular path to produce not only the expected 5-membered heterocyclic, 1, 1, 3, 3- ...
Related Articles:
[Sekeguchi,A.; Ando,W. Journal of the American Chemical Society, 1984 , vol. 106, p. 1486]
[Hussmann, Gregory; Wulff, William D.; Barton, Thomas J. Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1263 - 1269]
[Hussmann, Gregory; Wulff, William D.; Barton, Thomas J. Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1263 - 1269]
[Hussmann, Gregory; Wulff, William D.; Barton, Thomas J. Journal of the American Chemical Society, 1983 , vol. 105, # 5 p. 1263 - 1269]
[Tanaka; Okawara Bulletin of the Chemical Society of Japan, 1955 , vol. 28, p. 364]