Highly Efficient Etherification of Silanes by Using a Gold Nanoparticle Catalyst: Remarkable Effect of O2

T Mitsudome, Y Yamamoto, A Noujima…

Index: Mitsudome, Takato; Yamamoto, Yuya; Noujima, Akifumi; Mizugaki, Tomoo; Jitsukawa, Koichiro; Kaneda, Kiyotomi Chemistry - A European Journal, 2013 , vol. 19, # 43 p. 14398 - 14402

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Citation Number: 12

Abstract

Silyl ethers are of great importance and widely applicable materials for the synthesis of elastomers,[1a] coatings,[1b] fibers,[1c] and biomedical materials,[1d] besides for reagents [1e] and protecting groups for alcohols [1f] in organic synthesis. Generally, silyl ethers have been synthesized through the reactions of chlorosilanes [2] or disilazanes [3] with alcohols in the presence of a base such as pyridine. However, chlorosilanes are often not ...

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