Solvomercuration-demercuration. IV. Monohydration of representative dienes via oxymercuration-demercuration

HC Brown, PJ Geoghegan Jr, GJ Lynch…

Index: Brown,H.C. et al. Journal of Organic Chemistry, 1972 , vol. 37, # 12 p. 1941 - 1947

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Citation Number: 32

Abstract

Conclusion The oxymercuration-demercuration of olefins has previously been shown to be a highly convenient synthetic method for the Markovnikov hydration of olefins. The present paper has demonstrated a wide range of reactivity accompanying variation of olefin structure. Accordingly, considerable selectivity in the monooxymerauration of dienes is expected. Steric factors play a major role in determining the reactivity of hydrocarbon ...

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