FT??IR kinetic and product study of the Br??initiated oxidation of dimethyl sulfide

T Maurer, I Barnes, KH Becker

Index: Maurer; Barnes; Becker International Journal of Chemical Kinetics, 1999 , vol. 31, # 12 p. 883 - 893

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Citation Number: 6

Abstract

Abstract An FT-IR kinetic and product study of the Br-atom-initiated oxidation of dimethyl sulfide (DMS) has been performed in a large-volume reaction chamber at 298 K and 1000- mbar total pressure as a function of the bath gas composition (N 2+ O 2). In the kinetic investigations using the relative kinetic method, considerable scatter was observed between individual determinations of the rate coefficient, suggesting the possibility of interference ...