An Efficient Total Synthesis of (2E, 4E, 7R)??Farnesa??2, 4, 10??triene from (R)??(+)??Citronellal

J Li, Z Liu, J Lan, Y Li

Index: Li, Jing; Liu, Zuosheng; Lan, Jiong; Li, Yulin Journal of the Chinese Chemical Society, 1999 , vol. 46, # 2 p. 259 - 262

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Abstract

Abstract (2E, 4E, 7R)-farnesa-2, 4, 10-triene (Caparratriene)(1), a novel sesquiterpene hydrocarbon with significant growth inhibitory activity against CEM leukemia cells, was first synthesized from (R)-(+)-citronellal (2) by employing titanium-induced intermolecular carbonyl-coupling as the key step. The absolute configuration of (+)-Caparratriene was determined to be 7R.

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An Efficient Total Synthesis of (2E, 4E, 7R)??Farnesa??2, 4, 10??triene from (R)??(+)??Citronellal

Abstract

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