Journal of Organometallic Chemistry

Redox-untersuchungen an jodboranen VI. Zur kenntnis von diborylsulfanen, R 2 BS x-BR 2

W Siebert, E Gast, M Schmidt

Index: Siebert,W. et al. Journal of Organometallic Chemistry, 1970 , vol. 23, p. 329 - 342

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Citation Number: 15

Abstract

Abstract The redox reaction between dialkyliodoboranes and sulfur as well as the reaction of dialkylhaloboranes with H 2 S 2 or Na 2 S 2 leads to the formation of bis-(dialkylboryl) disulfanes, R 2 BSS-BR 2 (VI). This new class of compounds exhibits a high thermal, but a low hydrolytical, stability. Attempts to obtain diborylsulfanes, R 2 BS-BR 2 (V), by removing one sulfur atom from (VI) result in products formed by the rearrangement of (V). The ...

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