Synthesis and Structure of Tris (trialkylstannyl)??and Tris (dialkylhalostannyl) amines; Stabilization of the Sn3N Skeleton by Intramolecular Sn–X–Sn Bridges

…, C Kober, C Neumann, H Nöth, M Schmidt…

Index: Appel, Andrea; Kober, Christian; Neumann, Christine; Noeth, Heinrich; Schmidt, Martin; Storch, Wolfgang Chemische Berichte, 1996 , vol. 129, # 2 p. 175 - 189

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Citation Number: 14

Abstract

Abstract Tris (triorganylstannyl) amines (R 2 R'Sn) 3 N (1, 2) with substituents R= R'= Me, Bu or R= Me and R'= iPr, tBu are obtained by metathesis from R 2 R'SnX and NaNH 2 in liquid ammonia or by transamination of R 3 SnNMe 2 with NH 3. Tris (diorga-nylhalostannyl) amines (R 2 XSn) 3 N (3) are synthesized by stannazane cleavage of (Me 3 Sn) 3 N (1) with R 2 SnX 2. Information from multinuclear magnetic resonance spectra ascertain the ...