The Journal of Organic Chemistry

(Trimethylsilyl) allenes as propargylic anion equivalents: synthesis of homopropargylic alcohols and ethers

RL Danheiser, DJ Carini

Index: Danheiser, Rick L.; Carini, David J. Journal of Organic Chemistry, 1980 , vol. 45, # 19 p. 3925 - 3927

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Citation Number: 92

Abstract

Experimental Section Most apparatuses were as beforeG4 All materials used in this work, except those listed below, were reagent-grade commercial samples. 1,16-Dibromohexadecane was prepared by the symmetric anodic coupling of 9-bromononanoic acid" in a modification12 of Woolford's pr0~edure.l~ The cell was that previously de~cribed.~ The compound was obtained in 30% yield, mp 51.5-52.5 "C, from hexane [lit.13 mp 53.5-55.0 "C]. m- and p-( ...

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