RESEARCHES ON PYRIMIDINES. LXXVII. THE ALKYLATION OF 2-MERCAPTOPYRIMIDINES.

TB Johnson, RC Moran

Index: Johnson; Moran Journal of the American Chemical Society, 1915 , vol. 37, p. 2595

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Abstract

Johnson and Haggard'made the observation that, when n-allylmercapto-4-methyl-6- oxypyPimidine (I) undergoes alkylation in alcoholic solution and in the presence of sodium ethylate, there is no tendency, apparently, for the alkyl group of the halide to substitute in position 3 of the pyrimidine ring to form a compound corresponding to Formula 11. Either an imido ester combination (IV) is formed or a mixture of this with a 1-alky1 derivative as ...

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