Helvetica Chimica Acta

Notiz über eine regiospezifische Methode zur Herstellung von konjugierten Cyclohexadienen Über synthetische Methoden, 11. Mitteilung

A Rüttimann, A Wick, A Eschenmoser

Index: Ruettimann,A. et al. Helvetica Chimica Acta, 1975 , vol. 58, p. 1450 - 1455

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Citation Number: 16

Abstract

Abstract β, γ-unsaturated δ-hydroxy-cyclohexene carboxylic acids undergo a smooth decarboxylative elimination when treated with DMF-dineopentylacetal in an unpolar solvent. The reaction provides a method for the regiospecific preparation of 1, 3-cyclohexadiene derivatives under non-isomerizing conditions, starting from easily accessible and structurally variable intermediates.

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