Australian Journal of Chemistry

Dienone-pheno1 rearrangement studies. 5-Hydroxy-4a-methyl-5, 6, 7, 8-tetra-hydronaphthalen-2 (4aH)-one and 5-Acetoxy-4a-methyl-5, 6, 7, 8-tetrahydronaphthalen- …

KH Bell

Index: Bell,K.H. Australian Journal of Chemistry, 1972 , vol. 25, p. 1117 - 1124

Full Text: HTML

Citation Number: 0

Abstract

Abstract Attempted synthesis of the first of the title compounds indicates that it undergoes a spontaneous dienone-phenol rearrangement involving ring opening to yield 4-methyl-5, 6, 7, 8-tetrahydronephthalene-l, 8-diol the structure of which has been confirmed by an unambiguous synthesis of its Ar-methyl ether. The second of the title compounds has been synthesized and undergoes an acid-catalysed dienone-phenol rearrangement in acetic ...

Related Articles:

Halogenation of benzyl-and (heteroaromatic methyl) cobaloximes: direct competition between ring halogenation and cobalt-carbon bond cleavage

[Gupta, B. D.; Kumar, Manoj; Roy, Sujit Inorganic Chemistry, 1989 , vol. 28, p. 11 - 18]

Collisionally induced dissociation in the study of A-ring hydroxylated vitamin D type compounds

[Young, David C.; Vouros, Paul; Holick, Michael F.; Higuchi, Tetsuo Analytical Chemistry, 1992 , vol. 64, # 8 p. 837 - 842]

A simple and regioselective α-bromination of alkyl aromatic compounds by two-phase electrolysis

[Raju; Kulangiappar; Anbu Kulandainathan; Muthukumaran Tetrahedron Letters, 2005 , vol. 46, # 41 p. 7047 - 7050]

Electrophilic bromination of phenol ethers in superacid solution using alkali bromide

[Cherry, Ghassan; Culmann, Jean-Christophe; Sommer, Jean Tetrahedron Letters, 1990 , vol. 31, # 14 p. 2007 - 2010]

Mechanism of isomerization of ortho or para bromo phenols in superacids

[Jacquesy, Jean-Claude; Jouannetaud; Marie-Paule Tetrahedron Letters, 1982 , vol. 23, # 16 p. 1673 - 1676]

More Articles...