Synlett

New phosphine-functionalized N-heterocyclic carbene ligands for palladium-catalyzed hydroarylation reaction

J Zhong, JH Xie, AE Wang, W Zhang, QL Zhou

Index: Zhong, Jun; Xie, Jian-Hua; Wang, Ai-E.; Zhang, Wei; Zhou, Qi-Lin Synlett, 2006 , # 8 p. 1193 - 1196

Full Text: HTML

Citation Number: 30

Abstract

Abstract Novel triarylphosphine-functionalized imidazolinium salts have been prepared and successfully applied in palladium-catalyzed hydroarylation of bicyclic olefins. Under reductive conditions (HCOOH, Et 3 N), the complexes generated in situ from imidazolinium salts and Pd (OAc) 2 catalyzed the hydroarylation of bicyclic alkenes with aryl iodides, providing the hydroarylation products with high turnover numbers (TON, up to 1.9· 10 5) ...

Related Articles:

Alkyl-and arylsubstituted ketenedithioacetal tetroxides: Diels-alder reactivity and reductive desulfonylation of the adducts

[Tetrahedron, , vol. 48, # 8 p. 1485 - 1496]

Alkyl-and arylsubstituted ketenedithioacetal tetroxides: Diels-alder reactivity and reductive desulfonylation of the adducts

[Tetrahedron, , vol. 48, # 8 p. 1485 - 1496]

Esters synthesis by addition of monocarboxylic acids to exo-5-substituted bicyclo [2.2. 1] hept-2-ene hydrocarbons

[Russian Journal of Organic Chemistry, , vol. 39, # 2 p. 180 - 182]

Highly efficient phosphapalladacyclic catalysts for the hydroarylation of norbornene

[Brunel, Jean Michel; Heumann, Andreas; Buono, Gerard Angewandte Chemie - International Edition, 2000 , vol. 39, # 11 p. 1946 - 1949]

More Articles...