Magnetic properties of anhydrous and hydrated dimethylphosphinates of manganese (II). The crystal and molecular structure of poly-bis (μ-dimethylphosphinato) …

…, SJ Rettig, RC Thompson, J Trotter

Index: Cicha, Walter V.; Haynes, John S.; Oliver, Katherine W.; Rettig, Steven J.; Thompson, Robert C.; Trotter, James Canadian Journal of Chemistry, 1985 , vol. 63, p. 1055 - 1062

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Citation Number: 25

Abstract

The dimethylphosphinate of manganese (II), Mn [(CH3) 2PO2] 2, and its dihydrate have been prepared and studied using magnetic susceptibility, differential scanning calorimetry, and electronic and vibrational spectroscopic methods. The dihydrate was obtained in crystalline form and a single crystal X-ray diffraction study revealed a polymeric structure. Crystals of poly-bis (μ-dimethylphosphinato) diaquomanganese (II) are monoclinic, a= ...