The Journal of organic chemistry

Guanidine/Pd (OAc) 2-catalyzed room temperature Suzuki cross-coupling reaction in aqueous media under aerobic conditions

S Li, Y Lin, J Cao, S Zhang

Index: Li, Shenghai; Lin, Yingjie; Cao, Jungang; Zhang, Suobo Journal of Organic Chemistry, 2007 , vol. 72, # 11 p. 4067 - 4072

Full Text: HTML

Citation Number: 141

Abstract

A highly efficient Pd (OAc) 2/guanidine aqueous system for the room temperature Suzuki cross-coupling reaction has been developed. The new water-soluble and air-stable catalyst Pd (OAc) 2⊙(1f) 2 from Pd (OAc) 2 and 1, 1, 3, 3-tetramethyl-2-n-butylguanidine (1f) was synthesized and characterized by X-ray crystallography. In the presence of Pd (OAc) 2⊙(1f) 2, coupling of arylboronic acids with a wide range of aryl halides, including aryl iodides, ...

Related Articles:

Suzuki coupling reaction catalyzed heterogeneously by Pd (salen)/polyoxometalate compound: another example for synergistic effect of organic/inorganic hybrid

[Tong, Jinhui; Wang, Haiyan; Cai, Xiaodong; Zhang, Qianping; Ma, Hengchang; Lei, Ziqiang Applied Organometallic Chemistry, 2014 , vol. 28, # 2 p. 95 - 100]

Palladium-nanoparticle-catalyzed 1, 7-palladium migration involving C–H activation, followed by intramolecular amination: regioselective synthesis of N 1- …

[Al-Amin, Mohammad; Akimoto, Masayoshi; Tameno, Tsuyoshi; Ohki, Yuuta; Takahashi, Naoyuki; Hoshiya, Naoyuki; Shuto, Satoshi; Arisawa, Mitsuhiro Green Chemistry, 2013 , vol. 15, # 5 p. 1142 - 1145]

Synthesis of a novel C 2-symmetric thiourea and its application in the Pd-catalyzed cross-coupling reactions with arenediazonium salts under aerobic conditions

[Dai, Mingji; Liang, Bo; Wang, Cuihua; Chen, Jiahua; Yang, Zhen Organic Letters, 2004 , vol. 6, # 2 p. 221 - 224]

Palladium??Catalyzed Cross??Coupling of Organozinc Bromides with Aryl Iodides in Perfluorinated Solvents

[Betzemeier, Bodo; Knochel, Paul Angewandte Chemie (International Edition in English), 1997 , vol. 36, # 23 p. 2623 - 2624]

Reusable, Polystyrene??Resin??Supported, Palladium??Catalyzed, Atom??Efficient Cross??Coupling Reaction of Aryl Halides with Triarylbismuths

[Zhou, Wen-Jun; Wang, Ke-Hu; Wang, Jin-Xian; Huang, Dan-Feng European Journal of Organic Chemistry, 2010 , # 3 p. 416 - 419]

More Articles...