Synthesis of vinyl selenides or sulfides and ketene selenoacetals or thioacetals by nickel (II) vinylation of sodium benzeneselenolate or benzenethiolate

HJ Cristau, B Chabaud, R Labaudiniere…

Index: Cristau, H. J.; Chabaud, B.; Labaudiniere, R.; Christol, H. Journal of Organic Chemistry, 1986 , vol. 51, # 6 p. 875 - 878

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Citation Number: 76

Abstract

A number of useful functional group transformations can be achieved with vinyl selenides or sulfides. Owing to their ability to stabilize carbanionic intermediates for further functionalization and/or the easy removal of the metalloid, they have been widely used in organic synthesis. As a matter of fact, their preparations have held attention these past years, and several methods have been proposed. The preparations of vinyl senelides ...

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