Tetrahedron Letters

Grignard allylic substitution reaction catalyzed by 1, 2, 3-triazol-5-ylidene magnesium complexes

R Nomura, Y Tsuchiya, H Ishikawa, S Okamoto

Index: Nomura, Ryosuke; Tsuchiya, Yuji; Ishikawa, Hiroyuki; Okamoto, Sentaro Tetrahedron Letters, 2013 , vol. 54, # 11 p. 1360 - 1363

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Citation Number: 6

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Allylic chlorides and phosphates reacted with alkyl-Grignard reagent in an S N 2′-selective manner in the presence of a catalytic amount of 1,2,3-triazol-5-ylidenes to provide α-branched alkenes. ... The S N 2′-selective Grignard-allylic substitution reactions were effectively catalyzed by ...

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