Synthetic communications

Ethyl 4-(diethoxyphosphinyl)-3-oxobutanoate: Selective synthesis of β-keto phosphonates

C Pisani, DF Schneider, PCR Venter

Index: Du Pisani, Charl; Schneider, David F.; Venter, Pieter C. R. Synthetic Communications, 2002 , vol. 32, # 2 p. 305 - 314

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Citation Number: 5

Abstract

The selective synthesis of ethyl 4-(diethoxyphosphinyl)-3-oxobutanoate (7) and the utilization of its trimethylsilyl enolether (14) in a tandem desilylation Horner-Wittig condensation is illustrated. ... The selective synthesis of ethyl 4-(diethoxyphosphinyl)-3-oxobutanoate (7) and the utilization of its trimethylsilyl enolether (14) in a tandem desilylation Horner-Wittig condensation is illustrated. ... View all references deprotection of the reaction products was still an ...

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