Organic letters

Reagent-controlled stereoselective iodolactonizations

J Haas, S Piguel, T Wirth

Index: Haas, Juergen; Piguel, Sandrine; Wirth, Thomas Organic Letters, 2002 , vol. 4, # 2 p. 297 - 300

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Citation Number: 104

Abstract

Iodocyclizations are important transformations and among stereocontrolled iodocyclizations mostly substrate-controlled versions using a chiral auxiliary have been successfully investigated. This work reports on stereoselective reagent-controlled iodolactonizations applying a new method using a combination of ICl and a primary amine leading to the highest selectivities known so far.

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