Structural and conformational properties of fluoroformic acid anhydride, FC (O) OC (O) F

…, M Berkei, H Pernice, H Willner…

Index: Pernice, Holger; Berkei, Michael; Henkel, Gerald; Willner, Helge; Argueello, Gustavo A.; McKee, Michael L.; Webb, Thomas R. Angewandte Chemie - International Edition, 2004 , vol. 43, # 21 p. 2843 - 2846

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Citation Number: 7

Abstract

Fluoroformic acid anhydride is formed by reacting gaseous FC (O) OOC (O) F with CO. In the gas phase, the main conformer exhibits synperiplanar C 2 symmetry, which is the only conformer in the solid state. In the gas phase and in the crystal, the structural parameters are nearly identical.

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