Regioselectivity in the reductive bond cleavage of diarylalkylsulfonium salts: Variation with driving force and structure of sulfuranyl radical intermediates

…, P Thomsen, S Ullah, J Krake…

Index: Lan, J. Y.; Schuster, Gary B. Journal of the American Chemical Society, 1985 , vol. 107, # 23 p. 6710 - 6711

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Citation Number: 12

Abstract

... Journal of the ... j Initiated by photolysis at 300 nm, with [Ph 3 P] = 0.12 M; 4-tolyltriphenylphosp horanyl radical was the reducing agent.(13). Sulfonium salt 1-PF 6 is photocleaved by direct irradiation at 300 nm. ... yield a, expt, TolH, TolSEt, Tol 2 S, F b. 1, 18, 26, 50, 0.51. 2, 16, 23, 45, ...

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