Tetrahedron Letters

The mechanism of enzymatic and biomimetic oxidations of aromatic sulfides and sulfoxides

E Baciocchi, O Lanzalunga, F Marconi

Index: Baciocchi, Enrico; Lanzalunga, Osvaldo; Marconi, Francesco Tetrahedron Letters, 1994 , vol. 35, # 52 p. 9771 - 9774

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Citation Number: 39

Abstract

Abstract Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C H and/or C S bond cleavage), which suggests the operation of an oxygen transfer mechanism.

Switchable Palladium-Catalyst Reaction of Bromomethyl Sulfoxides, CO, and N-Nucleophiles: Aminocarbonylation at Csp3 versus Oxidative Carbonylation of Amines

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[Jia, Tiezheng; Bellomo, Ana; Baina, Kawtar El; Dreher, Spencer D.; Walsh, Patrick J. Journal of the American Chemical Society, 2013 , vol. 135, # 10 p. 3740 - 3743]