Pyrrole studies. 22.[4. pi.+ 2. pi.] Cycloaddition reactions with vinylpyrroles

…, WP Rosenthal, J Sepulveda Arques

Index: Jones, R. Alan; Marriott, Michael T.P.; Rosenthal, W. Philip; Arques, Jose Sepulveda Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4515 - 4519

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Citation Number: 51

Abstract

The synthesis of 3-hallo-3-methyldiazirines by oxidation sf acetamidine precursors has become the standard procedure since Graham's original report.'In the study of reactions of hydrogen atoms with 3-chloro-3-methyldiazirine it was crucial to an understanding of the mechanism to prepare the trideuterio compound. 2 This compound is known3 but no synthetic procedure has been reported. We now report the procedure for the synthesis of ...