Functionally substituted organotin compounds: I. Preparation and hydrostannation of stannylated allylic alcohols and related compounds

A Amamria, TN Mitchell

Index: Amamria, A.; Mitchell, T. N. Journal of Organometallic Chemistry, 1980 , vol. 199, # 1 p. 49 - 54

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Citation Number: 6

Abstract

Abstract Hydrostannation of 1-alkynols leads to the formation of the corresponding triorganostannylalkenols in good yields. The main product is the trans-isomer, while cis-and α-products are formed in lower yields. In some cases the stannyl alkenols can be further hydrostannated to give distannyl alkanols. 13 C and 119 Sn NMR data for the organotin compounds are presented and discussed.