Journal of the American Chemical Society

Unsaturated Amines. XIV. The Mercuric Acetate Oxidation of Substituted Pyrrolidines1

NJ Leonard, AG Cook

Index: Leonard; Cook Journal of the American Chemical Society, 1959 , vol. 81, p. 5627,5630

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Citation Number: 49

Abstract

RECEIVED hfAY 23, 1959-4 series of methyl-substituted pyrrolidines has been used to indicate the synthetic potentialities of the mercuric acetate oxidation of saturated tertiary amines containing a five-membered ring. The l,%, 1, 2, 5-, 1, 3, 4-and 1, 2, 2, 5-substituted pyrrolidines yield the corresponding A2-pyrrolines. In 1, 2, 2-trimethylpyrrolidine the double bond is introduced at the unsubstituted e-carbon, and the product is the dimer, l,~, 5- ...

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