Tetrahedron letters

Optically active cyclic allylsilanes: Preparation by asymmetric hydrosilylation and anti stereochemistry in SE'reactions

…, K Kabeta, T Yamamoto, K Tamao, M Kumada

Index: Hayashi, Tamio; Kabeta, Keiji; Yamamoto, Tsunehiro; Tamao, Kohei; Kumada, Makoto Tetrahedron Letters, 1983 , vol. 24, # 50 p. 5661 - 5664

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Citation Number: 91

Abstract

Abstract Reaction of optically active cyclic allylsilanes,(S)-3-(trimethylsilyl) cyclopentene and- cyclohexene, which are prepared by palladium-catalyzed asymmetric hydrosilylation of cyclic dienes, with ethylene oxide in the presence of titanium chloride proceeded with anti stereochemistry to give (R)-3-(2-hydroxyethyl) cyclopentene and-cyclohexene, respectively.

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