Thiol peroxidase activity of diorganyl tellurides

…, D Stern, M Pelcman, CM Andersson

Index: Engman, Lars; Stern, David; Pelcman, Mikael; Andersson, Carl M. Journal of Organic Chemistry, 1994 , vol. 59, # 8 p. 1973 - 1979

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Citation Number: 106

Abstract

A number of diorganyl tellurides, including diary1 tellurides, diheteroaryl tellurides, and alkyl aryl and dialkyl tellurides, were found to catalyze the reaction of hydrogen peroxide with thiols. The thiol peroxidase activity of the compounds was assessed by using a lH NMR method previously developed in our laboratories. In this assay, thiols (N-acetylcysteine, tert- butyl mercaptan, and 1-octyl mercaptan) were oxidized in the presence of hydrogen ...

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