Stereoselective Radical Aryl Migration Reactions from Sulfur to Carbon

M Bossart, R Fässler, J Schoenberger…

Index: Bossart, Martin; Faessler, Roger; Schoenberger, Jan; Studer, Armido European Journal of Organic Chemistry, 2002 , # 16 p. 2742 - 2757

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Citation Number: 9

Abstract

Abstract Stereoselective aryl migration reactions from sulfur in sulfonates and sulfonamides to C-centered radicals are reported. The 1, 5-aryl migration from sulfur to differently substituted C-centered radicals could be performed with high yields and selectivities. Functionalized aryl groups could also be transferred by this new method. A model to explain the stereochemical outcome of the reaction is presented and some mechanistic aspects of ...