Tetrahedron

Photoinduced electron transfer reactions of benzyl phenyl sulfides promoted by 9, 10-dicyanoanthracene

E Baciocchi, C Crescenzi, O Lanzalunga

Index: Baciocchi, Enrico; Crescenzi, Cristina; Lanzalunga, Osvaldo Tetrahedron, 1997 , vol. 53, # 12 p. 4469 - 4478

Full Text: HTML

Citation Number: 49

Abstract

The photoinduced oxidation of benzyl phenyl sulfides 1–3 has been investigated in MeCN using 9, 10-dicyanoanthracene as sensitizer in the presence of O2. In this reaction a sulfide radical cation is formed, which undergoes one or more of the three main reaction pathways opened to these species: C S bond cleavage, C H bond cleavage and S-oxidation. The former route (leading to benzylic products) was observed with all the substrates ...

Related Articles:

A kinetic evaluation of carbon-hydrogen, carbon-carbon, and carbon-silicon bond activation in benzylic radical cations

[Freccero, Mauro; Pratt, Albert; Albini, Angelo; Long, Conor Journal of the American Chemical Society, 1998 , vol. 120, # 2 p. 284 - 297]

A kinetic evaluation of carbon-hydrogen, carbon-carbon, and carbon-silicon bond activation in benzylic radical cations

[Freccero, Mauro; Pratt, Albert; Albini, Angelo; Long, Conor Journal of the American Chemical Society, 1998 , vol. 120, # 2 p. 284 - 297]

Establishment of the C− NO Bond Dissociation Energy Scale in Solution and Its Application in Analyzing the Trend of NO Transfer from C-Nitroso Compound to Thiols

[Li, Xin; Zhu, Xiao-Qing; Zhang, Fan; Wang, Xiao-Xiao; Cheng, Jin-Pei Journal of Organic Chemistry, 2008 , vol. 73, # 6 p. 2428 - 2431]

1-Substituted 4, 6-Diphenyl-2-methylthiopyridinium Salts as Versatile Intermediates in Organic Synthesis: Conversion of Arylmethanamines to Arylacetonitriles, …

[Fresneda, P. M.; Lidon, M. J.; Molina, P.; Vilaplana, M. J. Synthesis, 1981 , # 9 p. 711 - 714]

1-Substituted 4, 6-Diphenyl-2-methylthiopyridinium Salts as Versatile Intermediates in Organic Synthesis: Conversion of Arylmethanamines to Arylacetonitriles, …

[Fresneda, P. M.; Lidon, M. J.; Molina, P.; Vilaplana, M. J. Synthesis, 1981 , # 9 p. 711 - 714]

More Articles...