Tetrahedron letters

Regioselective palladium-catalyzed allylic alkylations

Y Dong, P Teesdale-Spittle, JO Hoberg

Index: Dong, Ying; Teesdale-Spittle, Paul; Hoberg, John O. Tetrahedron Letters, 2005 , vol. 46, # 2 p. 353 - 355

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Citation Number: 21

Abstract

Recently, we required acid 2 that we envisioned could arise from a palladium catalyzed dealloxycarbonylation 19 of 3, which would be assembled in a stereoselective manner using an AAA reaction and 4, Scheme 1. Given that the use of 4 in the AAA reaction is novel in terms of regiochemistry, we present herein its use in the AAA thus providing further information on the scope of this reaction. ... Formation of 4 involves a straightforward synthesis involving the known diol ...