Catalysis by di-n-butyltin oxide of a tertiary ketol rearrangement: synthesis of intermediates and analogues of valine and isoleucine biosynthesis

DHG Crout, DL Rathbone

Index: Crout, David H. G.; Rathbone, Daniel L. Journal of the Chemical Society, Chemical Communications, 1987 , # 4 p. 290 - 291

Full Text: HTML

Citation Number: 12

Abstract

Catalysis by Di-n-butyltin Oxide of a Tertiary Ketol Rearrangement: Synthesis of Intermediates and Analogues of Valine and lsoleucine Biosynthesis ... David HG Crout* and Daniel L. Rathbone Department of Chemistry, University of Warwick, Coventry CV4 7AL, U. K. ... Di-n-butyltin oxide efficiently catalyses the rearrangement of 3-hydroxy-2-oxocarboxylic acid esters into the corresponding 2-hydroxy-3-oxo-esters, in a reaction that simulates the reversible rearrangement ...

Related Articles:

Cerium??Catalyzed α??Hydroxylation Reactions of α??Cyclopropyl β??Dicarbonyl Compounds with Molecular Oxygen

[Christoffers, Jens; Kauf, Thomas; Werner, Thomas; Roessle, Michael European Journal of Organic Chemistry, 2006 , # 11 p. 2601 - 2608]

Synthesis of 2-hydroxy-3-oxocarboxylic esters from the corresponding α, β-unsaturated esters by a simple one-step procedure

[Crout, D. H. G.; Rathbone, D. L. Synthesis, 1989 , # 1 p. 40 - 42]

Cerium??Catalyzed α??Hydroxylation Reactions of α??Cyclopropyl β??Dicarbonyl Compounds with Molecular Oxygen

[Christoffers, Jens; Kauf, Thomas; Werner, Thomas; Roessle, Michael European Journal of Organic Chemistry, 2006 , # 11 p. 2601 - 2608]

More Articles...