Tetrahedron

An alternate route to a quassin synthon: Comparison of 1, 3-diaxial and peri steric interferences in hydride reductions

C Schmidt, T Breining

Index: Schmidt,C.; Breining,T. Tetrahedron, 1983 , vol. 39, p. 3929

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Citation Number: 4

Abstract

It is shown that in so far as hydride reductions are concerned the following order of steric hindrance can be stated: two 1,3-diaxial peri one 1,3-diaxial. An alternate route is described to quassin synthon 2 from Diels-Alder adduct 1 in eleven steps. ... Telraheilrrn Vol 39. No :3. pp 39:9 10 393?. 1983 Pnnlcd in Grcal Bnlain 004(M020'83 S3 00 + 00 PergatTlon Press Ltd AN ALTERNATE ROUTE TO A QUASSIN SYNTHON COMPARISON OF 1,3-DIAXIAL AND PERI STERIC ...