Journal of heterocyclic chemistry

Reaction between ethyl ω??chloroalkylimidates and hydrazides

M Bonanomi, L Baiocchi

Index: Bonanomi, Michele; Baiocchi, Leandro Journal of Heterocyclic Chemistry, 1983 , vol. 20, p. 1657 - 1660

Full Text: HTML

Citation Number: 6

Abstract

Abstract It is already known that ethyl ω-chloroalkylimidate hydrochlorides and aroyl hydrazides gave, when reacted together in boiling ethanol, 2-aryl-5-ω-haloalkyl-1, 3, 4- oxadiazoles. It has now been found that the reaction follows a different course in the presence of triethylamine. In particular, 2-aryl-5, 6, 7, 8-tetrahydro-1, 2, 4-triazolo [5, 1-α] pyridines were obtained from ethyl δ-chlorovalerimidate, whereas N-aroylaminoimino- ...