Über sterisch gehinderte freie radikale X. Zur darstellung von gemischt alkylierten zinnverbindungen Me2RSnX und MeR2SnX, R neopentyl, 1-methyl-cyclohexyl, X …

AF El-Farargy, WP Neumann

Index: El-Farargy, Ahmed F.; Neumann, Wilhelm P. Journal of Organometallic Chemistry, 1983 , vol. 258, # 1 p. 15 - 20

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Citation Number: 5

Abstract

Abstract A number of the compounds Me 2 RSnX (R neopentyl, 1-methylcyclohexyl; X Me, Cl, H) has been prepared for the first time. Generally, replacement of Me in a higher methylated precursor against Cl in polar medium by HgCl 2 has been shown to be the best way to obtain the halides mentioned. The hydrides are used for ESR measurements of the corresponding stannyl radicals.