Tetrahedron letters

α—Selective cross-coupling reaction of allyltrifluorosilanes: Remarkable ligand effect on the regiochemistry

Y Hatanaka, K Goda, T Hiyama

Index: Hatanaka, Yasuo; Goda, Ken-Ichi; Hiyama, Tamejiro Tetrahedron Letters, 1994 , vol. 35, # 35 p. 6511 - 6514

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Citation Number: 38

Abstract

Abstract The cross-coupling reaction of allyltrifluorosilanes with aryl halides or aryl triflates promoted by a fluoride salt takes place at the α-carbon of the allyltrifluorosilanes in the presence of a catalytic amount of PdCl 2 [Ph 2 P (CH 2) n PPh 2](n= 2, 3), giving allylic arenes with high regioselectivity.

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