First synthesis of cyclic organogermanium peroxides, 1, 2, 4, 5, 7, 8-hexaoxa-3-germonanes

AO Terent'ev, MM Platonov, IV Krylova…

Index: Terent'ev; Platonov; Krylova; Egorov; Nikishin Journal of Organometallic Chemistry, 2009 , vol. 694, # 12 p. 1786 - 1788

Full Text: HTML

Citation Number: 1

Abstract

First, previously unknown, cyclic organogermanium peroxides, 1, 2, 4, 5, 7, 8-hexaoxa-3- germonanes, were synthesized by the reaction of 1, 1′-dihydroperoxydi (cyclododecyl) peroxide with (di) alkyl (aryl) dihalogengermanes. The new compounds have a higher tendency to undergo hydrolysis compared to silicon-containing analogs.