Synthesis and 1H, 13C, 14N, 15N, 29Si NMR study of trimethylsilylquinolines and their methiodides

E Lukevics, E Leipiņš, I Segal, M Fleisher

Index: Lukevics, Edmunds; Liepins, Edvards; Segal, Izolda; Fleisher, Mendel Journal of Organometallic Chemistry, 1991 , vol. 406, # 3 p. 283 - 298

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Citation Number: 6

Abstract

Abstract 2-, 3-, 4-, 5-, 6-, 7-and 8-trimethylsilylquinolines and their methiodides as well as some 2-silyl-alkylquinolines were obtained by lithium synthesis in order to elucidate intramolecular donor-acceptor interactions between nitrogen and silicon atoms. 1 H, 13 C, 14 N, 15 N and 29 Si NMR spectra of the compounds were studied and quantum-chemical calculation of charges on individual atoms in the unsubstituted quinoline and in ...