The Journal of Organic Chemistry

Reactions of Perfluoroalkyl Nitriles. V. Synthesis of Perfluoroacyl Imidates1

HC Brown, CR Wetzel

Index: Brown,H.C.; Wetzel,C.R. Journal of Organic Chemistry, 1965 , vol. 30, p. 3724 - 3728

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Citation Number: 18

Abstract

Stable alkyl perfluoroacyl imidates, RFC (= NH) OR, were prepared by the base-catalyzed addition of methyl, isopropyl, and 2, 2, 2-trifluoroethyl alcohols to perfluoroalkyl nitriles. Tertiary alcohols did not produce imidates under the same conditions, apparently owing to ...