Fourier-transform infrared studies of the self-reaction of CH3O2 radicals

H Niki, PD Maker, CM Savage…

Index: Niki, H.; Maker, P. D.; Savage, C. M.; Breitenbach, L. P. Journal of Physical Chemistry, 1981 , vol. 85, # 7 p. 877 - 881

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Citation Number: 52

Abstract

Product studies were made with the FT IR method in the photooxidation of CH3N2CH3 and in the Cl-atominitiated oxidation of CHI in 02-N2 mixtures at 700 torr and 297 K. The major products were CH20, CH30H, and CH302H in both systems. A weak, broad absorption band centered at 1030 cm-'was assigned tentatively to CH3O2CH3 The resulta are consistent with the following primary and secondary reactions:(primary) 2CH302-2CH30+ O2 (la); ...

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