Journal of Chemical Research

The synthesis of thiobisphenols from 3-alkylphenols derived from natural phenolic lipids

JHP Tyman, RA Johnson

Index: Tyman, John H. P.; Johnson, Robert A. Journal of Chemical Research, 2005 , # 2 p. 116 - 118

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Abstract

3-Alkylphenols derived from renewable natural resources have been used to synthesise thiobisphenols by reaction with sulfur dichloride. In contrast to previous work, we have found that 3-alkylphenols give isomeric products, the major symmetrical, the 4, 4 '-thiobis compound, the minor symmetrical, 2, 2 '-thiobisphenol, and some of the believed unsymmetrical isomer. The role of the solvent and catalyst have been studied in the ...