Reactions of Trimethylsilyl Sulfate1

LH Sommer, GT Kerr, FC Whitmore

Index: Sommer; Kerr; Whitmore Journal of the American Chemical Society, 1948 , vol. 70, p. 446

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Citation Number: 14

Abstract

The Flood Reaction.-In 1933 Flood reported that treatment of a concentrated sulfuric acid solution of hexaethyldisiloxane with ammonium chloride or fluoride gives triethylchlorosilane or the corresponding fluor0 compound.* In connection with studies of organosilicon compounds, we have found this reaction extremely convenient for the preparation of large amounts of trialkylchloro-and trialkylfluorosilanes, when (certain modifications of the ...