N-monochlorination and N-monobromination of carbamates and carboxamides by sodium hypochlorite and hypobromite

C Bachand, H Driguez, JM Paton…

Index: Bachand,C. et al. Journal of Organic Chemistry, 1974 , vol. 39, # 21 p. 3136 - 3138

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Citation Number: 45

Abstract

Our studies on the chromous chloride promoted addition of N-chlorocarbamates to olefins2 led us to devise a convenient method for the preparation of N-monochlorocarbamates in high yield, free from the N, N-dichloro derivatives. This method was also applied to the preparation of N-monochlorocarboxamides and of N-monobromocarbamates and- carboxamides needed for the chromous chloride promoted addition studieszc and some ...