Journal of the American Chemical Society

Organic Peroxides. XVI. Acetylene Peroxides and Hydroperoxides—A New Class of Organic Peroxides

NA Milas, OL Mageli

Index: Milas; Mageli Journal of the American Chemical Society, 1952 , vol. 74, p. 1471

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Citation Number: 14

Abstract

The synthesis of a hitherto unknown class of organic peroxides, acetylene peroxides, is herein reported. Three types of this class of organic peroxides have been synthesized:(1) acetylene hydroperoxides comparable to acetylenecarbinols;(2) acetylene dihydroperoxides comparable to acetylene glycols; and (3) alkynyl peroxides Comparable to alkynyl ethers. These peroxides are unusually stable and, in this respect, are comparable to saturated ...