Mizoroki–Heck reactions of methyl acrylate in presence of a palladated rasta resin

A Derible, JM Becht, C Le Drian

Index: Derible, Antoine; Becht, Jean-Michel; Le Drian, Claude Tetrahedron Letters, 2013 , vol. 54, # 32 p. 4207 - 4209

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Citation Number: 8

Abstract

Mizoroki–Heck cross-couplings of aryl halides in the presence of a palladium catalyst supported on a rasta resin bearing diphenylphosphanyl ligands are reported. In particular, we show that tiny amounts of soluble palladium species leached from the polymeric support catalyze the reaction. A one-pot two steps preparation of alkenes from aryl bromides using a Finkelstein halogen exchange reaction is also described.