Synthesis of Planar Chiral N??Heterocyclic??Substituted Pyridinophanes

JJP Kramer, M Nieger, S Bräse

Index: Kramer, Joshua J. P.; Nieger, Martin; Braese, Stefan European Journal of Organic Chemistry, 2013 , # 3 p. 541 - 549

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Abstract

Abstract Four new planar chiral N-heterocyclic-substituted [2](1, 4) benzene [2](2, 5) pyridinophanes have been synthesized. With the attached pyrazole, triazole, tetrazole, and pyrimidine moieties, different N, N-chelating ligands that vary in the number of enclosed nitrogen atoms, ring size, and electronic properties were added to a mostly neglected class of pyridinophanes. Additionally, the known synthesis of the pyridinophane scaffold was ...

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