Stevensanaloge, Durch Nickelkomplexe Katalysierte Umlagerung Von Triarylphosphoryliden Und Darstellung Sowie Strukturbestimmung Von Phosphorylid?? …
F Heydenreich, A Mollbach, G Wilke…
Index: Heydenreich,F. et al. Israel Journal of Chemistry, 1972 , vol. 10, p. 293 - 319
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Citation Number: 44
Abstract
Abstract The Stevens rearrangement of the triarylphosphorusylids R 3 P= CHR′(III)(R′= H, CH 3, C 2 H 5) to diarylbenzylphosphines (V) is catalyzed by nickel complexes (eg,(COD) 2 Ni (I)). Attempts to prepare trimesitylphosphine-methylene result in direct formation of dimesityl (mesitylmethyl) phosphine (XII)—the first recorded direct Stevens rearrangement of a phosphorusylid. Phosphorusylids react with nickeltetracarbonyl without rearrangement ...
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