Preparation and Characterization of Tris (trimethylsilyl) germylzinc Chloride and Bis [tris (trimethylsilyl) germyl] zinc.

M Nanjo, T Oda, K Mochida

Index: Nanjo, Masato; Oda, Takashi; Mochida, Kunio Chemistry Letters, 2002 , # 1 p. 108 - 109

Full Text: HTML

Citation Number: 6

Abstract

The molecular structure of (Me 3 Si) 3 GeZnCl (1) has been determined by single-crystal X- ray diffraction. The germylzinc chloride 1 has a dimeric structure consisting of two μ-Cl atoms. The compound 1 reacted with (Me 3 Si) 3 GeLi in diethyl ether to give [(Me 3 Si) 3 Ge] 2 Zn (2), quantitatively. The structure of bis (germyl) zinc 2 has been also elucidated by X-ray diffraction.