Divergent Mechanistic Avenues to an Aliphatic Polyesteracetal or Polyester from a Single Cyclic Esteracetal

AE Neitzel, MA Petersen, E Kokkoli…

Index: Martin, Ryan T.; Camargo, Ludmila P.; Miller, Stephen A. Green Chemistry, 2014 , vol. 16, # 4 p. 1768 - 1773

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Citation Number: 4

Abstract

... mol) and MDO66 ([ZnEt 2 ] 0 = 2 mM, [MDO] 0 = 10.1 M, [BnOH] 0 = 84 mM, t polym = 72 ... neat monomer was calculated to be 81 °C (ΔH p 0 = −11.6 kJ/mol and ΔS p 0 = −52 ... The authors would like to thank Dr. Thomas Hoye for helpful discussions and Dr. Joseph Dalluge for help ...