Preparation of Sulfonic Acids from Unsaturated Compounds1

JS Showell, JR Russell, D Swern

Index: Showell,J.S. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 2853 - 2858

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Citation Number: 46

Abstract

A method of purifying It has been shown for the first time that Reaction paths for the oxidation free radical addition of thiolacetic acid to form thiolacetates, followed by hydrogen peroxide- acetic acid oxidation. reaction sequence permits the preparation of isomer-free terminal sulfonic acids from 1-olefins. 1-olefins by a partial, selective epoxidation procedure has also been described. methyl esters are obtained in high yield by reaction of sulfonic acids with ...