The Journal of Physical Chemistry

Disproportionation to combination ratios of alkoxy radicals with nitric oxide

P Morabito, J Heicklen

Index: Morabito, Paul; Heicklen, Julian Journal of Physical Chemistry, 1985 , vol. 89, # 13 p. 2914 - 2916

Full Text: HTML

Citation Number: 16

Abstract

The disproportionation to combination ratios were measured at 175 OC for the reactions RO+ l5NO-ROI5NO (2a) and RO+ I5NO-RCHO+ H15N0 (2b), with the following alkoxy radicals: C2H50, n-C3H70,? &&go, and i-C4H90. The alkoxy radical was generated by the thermal decomposition of the corresponding alkyl nitrite in the presence of I5NO. The rate of the corresponding isotopically enriched alkyl nitiite was measured by mass spectrometry ...

Related Articles:

Hydrolysis, nitrosyl exchange, and synthesis of alkyl nitrites

[Doyle, Michael P.; Terpstra, Jan W.; Pickering, Ruth A.; LePoire, Diane M. Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3379 - 3382]

Digital Halftoning Algorithms for Medical Imaging

[Reynolds; Adkins Journal of the American Chemical Society, 1929 , vol. 51, p. 284 Full Text Show Details Reynolds; Adkins Journal of the American Chemical Society, 1929 , vol. 51, p. 280,284]

THE RELATIONSHIP OF THE CONSTITUTION OF CERTAIN ALKYL HALIDES TO THE FORMATION OF NITROPARAFFINS AND ALKYL NITRITES

[Reynolds; Adkins Journal of the American Chemical Society, 1929 , vol. 51, p. 284]

Rate constants for the reactions of C2H5O, i??C3H7O, and n??C3H7O with NO and O2 as a function of temperature

[Fittschen; Frenzel; Imrik; Devolder International Journal of Chemical Kinetics, 1999 , vol. 31, # 12 p. 860 - 866]

The Thermal Decomposition of Nitrate Esters. III. n-Propyl Nitrate1

[Levy; Adrian Journal of the American Chemical Society, 1955 , vol. 77, p. 2015]

More Articles...